Plastic-cased dry cells



Dec. 2, 1952 A. F. DANlEL.

PLASTIC-CASED DRY CELLS Filed Aug. 2, 1950 FIG. 2

\ *IIIIIIIIM INVENTOR.

ARTHUR E DANIEL Patentecl Dec. 2, 1952 rLAsTio-oAsED DRY CELLS Arthur F. Daniel, Fair Haven, N. J., assigner to the United States of America as represented by the Secretary of the Army VApplication August 2, 1950, Serial No. 177,315

1 Claim.

(Granted under the act of March 3, 1883, as amended April 30, 1928; 370 O. G. 757) The invention described herein may be manufactured and used by o-r for the Government for governmental purposes, without the payment of any royalty thereon.

This invention relates to a cell container structure for primary batteries built up from dry cells aligned in series, and particularly from alkaline dry cells of the Zinc-mercurio oxide type.

It is an object of this invention to provide a cell container structure which materially simplifies many manufacturing problems and makes possible quick assembling of dry cells into high voltage batteries with the aid of plastic containers. `Other objects of this invention will become apparent for those skilled in the Eart from the following description and accompanying drawing of a cell container structure for primary batteries built up from alkaline dry cells of the zinc-mercurio oxide type.

In the drawing:

Figure l is a sectional view of one of the units or cartridge sections of the container structure according to my invention. Figure 2 is a sectional view of a battery built up with the aid of such units or cartridge sections as shown in Figure l, and Figure 3 is a fragmentary sectional View of a battery similar to Figure 2 showing a modified form of cartridge sections.

The cartridge section shown in Figure 1 consists of a cylindrical ring I of plastic insulating material such as polystyrene, polyethylene, hard rubber, neoprene, or other insulating high polymers. Inside the cylindrical ring I is arranged a partition wall 2 of electrically conductive material, preferably metal, which divides the interior of the cylindrical ring I into a housing 3 for the -anodic part of one cell and a housing 4 for the cathodic part of the adjacent cell.

The partition wall 2 preferably consists of a bi-metallic sheet, the diiferent metals being chosen so as to prevent undesired reactions between them -and the anodic and cathodic parts respectively. If the` cell container structure according to this invention is used for alkaline dry cells of the zinc-mercurio oxide type, the metal sheet 5 which faces the anodic part (zinc electrode) of one cell consists preferably of copper, brass, silver, tin or copper-plated steel, while the metal sheet '6, facing the cathodic part (mercurio oxide electrode) of the adjacent cell consists preferably of iron or steel. The two metal sheets 5 and I6 may be fastened -together for mechanic-a1 and electrical contact by welding or soldering or any other suitable and approved method. After fastening together they are then placed in the plastic mold as inserts. Instead of a loi-metallic plate, it is also possible to use a single amalgamated steel plate.

The partition wall 2 is molded into the plastic ring I in well known manner. To prevent leakage or creepage of electrolyte around the peripheral part of the partition Wall 2 the peripheral part of said bi-metallic plate is bifurcated and the peripheral parts of each single sheet prolongated so as to elongate the possible leakage and creepage path.

The plastic material from which the cylindrical ring I is made must be inert to the action of the electrolyte and any of the components used in the cell; it must also be capable of being made -to adhere to the metal of the bi-metallic plate 2.

Figure 2 shows a battery consisting of three cells and built up from two cartridge sections I2 and I3 and two end sections II and I4. The two cartridge sections I2 and I3 consist, as the cartridge section in Figure l, of a cylindrical ring I, a partition wall 2 comprising a copper disc 5 and a steel disc 6. The end cells II and I4 each consist of a half cartridge section, the end cell II being closed by a copper plate I5 while the end cell I4 is closed by a steel plate I6. In this Way a battery of three cells is built up each of the cells containing a zinc anode 2l] consisting of a compressed pellet of amalgam-ated zinc powder, a layer 2l of porous paper, fiber, felt or other suitable bibulous material capable of retaining sufficient electrolyte, and a cathode comprising an electronically conductive body containing an oxygen yielding compound such as mercuric oxide, silver oxide, lead peroxide or the like containing .in known manner conductive materials such Ias graphite, carbon black or the like. Instead of the zinc pellet 20 and bibulous layer 2I there may be used other well known anode `assemblies such as, for instance, a roll of corrugated zinc foil interleaved with a layer of bibulous material.

The structure shown in Figure 2 might, of course, be continued with a greater number of cartridge sections to get any desired Ivoltage. The cartridge sections are fastened or rigidly joined together by several known methods such as heat sealing or with ,the aid of lacquers or adhesives depending upon the type of plastic used for the manufacture of the cartridge sections.

In order to improve the sealing effect between the individual sections, it is advantageous to increase the surface of the edges of the cartridge sections, as shown in Figure 3 in which the cartridge sections 3| and 32 possess increased surfaces of the edges as indicated by the dotted sealing line 30. The end cartridge sections 33 and 34 must, of course, in this case be adequately formed. Any other type of edges might, of course, be used provided it increases they effective sealing between the cells.l

While I have described my invention in connection with a specic cell and a specific structure of such cell, I do not wish -to be limited either to the particular design or to the specific combination of internal elements referred to herein since it is evident that YVsihjii'lafr `structuresmight be used with any other cell system which does not gas during the life of proper materials are used.

What I claim is: In a primary battery built up the cell `prcu/ ided ,from` alkaline dry cells of the zinc-mercuricfoxide type aligned in series, a cell container structur coimlrisiiier stacked cartridge sections rigidly secured to one Kao anotherfea'ch of'sa'idcartridgel sections comprisingicylindri'cal f side walls of insulating' plastic material and partition Walls of electrically con-T' ductingmaterial'j s'aidpartition'w-alls being arranged? perpendicilarly to"v 1said"cylin"drical side wall'siand tightly sealed'into' the cylindricalside wallsgsaidfpartition Wall'sjformi'ng -at'once the top'iand the-'anodcterminal' of onevcell'and thel bott'onrv and" the' jcathodie"terminal 'ofv the adjacenti ce'llf each ofsa'id cartridge sections thereby 011 theallsaline electrolytevperipheral parts of each single sheet are bent Iand prolongated so as to separate said peripheral parts of eah-singlesheet by a maximum thickness` of fsaid insulatingplastic material and to elongate theipossible leakage and creepage path ARTHUR F. DANIEL.

REFERENCES CITED The vfollowingreferences are of record in the le of this upatent:

UNlTED. STATEsrATEN'rS Number Name .Date

2,525,270Vl Qlllnllell 'f l. OC. 10, ,1950 2,536,697 Ruben Jan. 2;,1951` Number Country 'Y Date 562,'780 Great'Britain July 14, 1944 5559,91,

GreatjBritain- Octjz, Y1944 

